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The nonlinear differential constitutive equation for molar energy of the strained body is obtained. It helps to define physical conditions, parameters and time to macroscopic fracture under non-stationary loading. Solution of equation brought forth the analytic function of material structural parameter, Zurkov durability formula and empirical relationships for properties of structural variation irreversibility. Experimentally and theoretically sound kinetic structure-and-energy law is stated for the uniaxial and combined stress state of the strained body.

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